The North Carolina State AFL–CIO is governed by an executive board of Vice Presidents (listed in alphabetical order by last name).

• David Anders: IAFF
• J.C. Bullock: ATU
• Will Cashion: IAMAW
• J. David Cox: AFGE
• Eddie Davidson, Jr.: NALC
• Lewis Dishmon: Workers United
• Edward Drescher: UA
• Randy Fulk: BCTGM
• Vernon Gammon: IBT
• Mike Gravinese: AFGE
• Calvin Griffin: USW
• Corey Hill: UAW
• Dianne Jackson: AFT
• Darryl Jackson: USW
• Henry Loftis: IUOE
• Keith Ludlum: UFCW
• Sharon Machovina: AFGE
• Tony McKinnon: APWU
• Barbara McKoy: Workers United
• Theodore McNeal, Jr.: IAMAW
• Melvin Montford: Constituency Groups
• Larry Murray: USW
• Richard O’Brien: IAFF
• Bonnie Overman, CWA
• Bob Riggins: UAW
• Jason Rosin: Central Labor Councils
• Craig Schadewald: NALC
• Brenda Scotland: GMP
• Larry Sorrells: APWU
• Scott Thrower: IBEW
• Alvin Warwick: IBEW
• Richard Westbrook: UTU